In Situ Determination of Au and Cu in Natural Pyrite by Near‐Infrared Femtosecond Laser Ablation‐Inductively Coupled Plasma‐Quadrupole Mass Spectrometry: No Evidence for Matrix Effects     

German Velásquez  Anastassia Y. Borisova  Stefano Salvi  Didier Béziat 《Geostandards and Geoanalytical Research》2012,36(3):315-324

Gold and copper concentrations were determined in natural pyrite by near‐infrared femtosecond LA‐ICP‐QMS, using both sulfide reference materials (pyrrhotite Po‐726 and in‐house natural chalcopyrite Cpy‐RM) and NIST SRM 610 as external calibrators. Firstly, using NIST SRM 610 as the external calibrator, we calculated the Au concentration in Po‐726 and the Cu concentration in Cpy‐RM. The calculated concentration averages for Au and Cu were similar to the values published for Po‐726 and Cpy‐RM, respectively. Secondly, we calculated Au and Cu concentrations taking NIST SRM 610 as an unknown sample and using Po‐726 and Cpy‐RM as external calibrators. Again, the average values obtained closely reflected the preferred concentrations for NIST SRM 610. Finally, we calculated Au and Cu concentrations in natural pyrite using sulfide and silicate reference materials as external calibrators. In both cases, calculated concentrations were very similar, independent of the external calibrator used. The aforementioned data, plus the fact that we obtained very small differences in relative sensitivity values (percentage differences are between 5% and 17% for ⁵⁷Fe, ⁶³Cu and ¹⁹⁷Au) on analyses of silicate and sulfide RMs, indicate that there were no matrix effects related to the differences in material composition. Thus, it is possible to determine Au and Cu in natural sulfides using NIST silicate glasses as an external calibrator.  相似文献   

Thermal bending of thin, anisotropic, clamped elliptic plates     

P.A.A Laura  C.A Rossit 《Ocean Engineering》1998,26(5):485-488

The present note deals with the exact analytical solution of thermal bending of clamped, anisotropic, elliptic plates in the case where the thermal field is given by an expression of the type T(x,y,z)=z(Ax²+Cxy+By²).The problem is of basic interest in some ocean and mechanical structural systems since anisotropic materials are commonly used in those fields. Obviously the case of an orthotropic material constitutes a particular situation of the problem under study.  相似文献   

Piešt'any–thermal H2S water and mud     

O. Franko 《Environmental Geology》1998,36(3-4):215-218

 Slovakia has very rich sources of mineral and thermal waters. One of the warmest is located in Piešt'any. Its discharge rate is 40 l/s; it is Ca-Mg-SO₄-HCO₃-Cl type with T.D.S. 1.4 g/l, H₂S 10 mg/l and temperature 68  °C. The waters seep on the spa island, which lies between the river Váh and its branch. The characteristics of the water and mud predestine the existence of this great spa in Slovakia. Its reputation is based on the treatment of rheumatic and neurological disesases. Received: 15 November 1996 · Accepted: 13 January 1998  相似文献   

Effects of mass loss for highly-irradiated giant planets     

W.B. Hubbard  M.F. Hattori  I. Hubeny 《Icarus》2007,187(2):358-364

We present calculations for the evolution and surviving mass of highly-irradiated extrasolar giant planets (EGPs) at orbital semimajor axes ranging from 0.023 to 0.057 AU using a generalized scaled theory for mass loss, together with new surface-condition grids for hot EGPs and a consistent treatment of tidal truncation. Theoretical estimates for the rate of energy-limited hydrogen escape from giant-planet atmospheres differ by two orders of magnitude, when one holds planetary mass, composition, and irradiation constant. Baraffe et al. [Baraffe, I., Selsis, F., Chabrier, G., Barman, T.S., Allard, F., Hauschildt, P.H., Lammer, H., 2004. Astron. Astrophys. 419, L13-L16] predict the highest rate, based on the theory of Lammer et al. [Lammer, H., Selsis, F., Ribas, I., Guinan, E.F., Bauer, S.J., Weiss, W.W., 2003. Astrophys. J. 598, L121-L124]. Scaling the theory of Watson et al. [Watson, A.J., Donahue, T.M., Walker, J.C.G., 1981. Icarus 48, 150-166] to parameters for a highly-irradiated exoplanet, we find an escape rate ∼¹⁰² lower than Baraffe's. With the scaled Watson theory we find modest mass loss, occurring early in the history of a hot EGP. In this theory, mass loss including the effect of Roche-lobe overflow becomes significant primarily for masses below a Saturn mass, for semimajor axes ?0.023 AU. This contrasts with the Baraffe model, where hot EGPs are claimed to be remnants of much more massive bodies, originally several times Jupiter and still losing substantial mass fractions at present.  相似文献   

Degree-one convection and the origin of Enceladus' dichotomy     

M. Grott  F. Sohl 《Icarus》2007,191(1):203-210

Recently, the Cassini spacecraft has detected ongoing geologic activity near the south pole of Saturn's moon Enceladus. In contrast, the satellite's north-polar region is heavily cratered and appears to have been geologically inactive for a long time. We propose that this hemispheric dichotomy is caused by interior dynamics with degree-one convection driving the south-polar activity. We investigate a number of core sizes and internal heating rates for which degree-one convection occurs. The numerical simulations imply that a core radius of less than 100±20 km and an energy input at a rate of 3.0 to 5.5 GW would be required for degree-one convection to prevail. This is within the range of the observed thermal power release near Enceladus' south pole. Provided that Enceladus is not fully differentiated, degree-one convection is found to be a viable mechanism to explain Enceladus' hemispheric dichotomy.  相似文献   

Mid-to-Far Infrared Spectral Energy Distribution of Galaxies in the Spitzer First Look Survey Field     

Xiao-Qing Wen    Hong Wu  Chen Cao  Xiao-Yang Xia  Department of Physics  Tianjin Normal University  Tianjin National Astronomical Observatories  Chinese Academy of Sciences  Beijing   《中国天文和天体物理学报》2007,7(2):187-198

We made model fitting to the mid-to-far infrared spectral energy distributions (SEDs) for different categories of galaxies in the main extragalactic field of the Spitzer First Look Survey with the aid of spectroscopic information from the Sloan Digital Sky Survey. We find that the mid-to-far infrared SEDs of HII galaxies, mixture type galaxies and LINERs can be well fitted by the one-parameter (α) dust model of Dale et al. plus the 13 Gyr dust-free elliptical galaxy model. The statistics of α values indicates that all these galaxies tend to be quiescent, although the HII galaxies are relatively more active than the LINERs. The mid- infrared SEDs of absorption galaxies are well fitted simply by the 13 Gyr dust-free elliptical galaxy template, and the near-to-mid infrared SEDs of QSOs can be represented by AGN NGC 5506.  相似文献   

Detecting Arctic snow and ice cover with FY-1D global data     

References： 《极地研究(英文版)》2007,18(1):54-62

Chinese meteorological satellite FY-1D can obtain global data from four spectral channels which include visible channel(0.58-0.68 μm) and infrared channels(0.84-0.89 μm,10.3-11.3 μm,11.5-12.5 μm).2366 snow and ice samples,2024 cloud samples,1602 land samples and 1648 water samples were selected randomly from Arctic imageries.Land and water can be detected by spectral features.Snow-ice and cloud can be classified by textural features.The classifier is Bayes classifier.By synthesizing five d ays classifying result of Arctic snow and ice cover area,complete Arctic snow and ice cover area can be obtained.The result agrees with NOAA/NESDIS IMS products up to 70%.  相似文献   

Conventions on thermal expansion modelling of radio telescopes for geodetic and astrometric VLBI   总被引：7，自引：6，他引：1  

Axel Nothnagel 《Journal of Geodesy》2009,83(8):787-792

Thermal expansion of radio telescopes has long been recognized as an effect which cannot be neglected in geodetic and astrometric VLBI data analysis if millimeter accuracy is desired. In this article, the author documents the conventions which are being set by the International VLBI Service for Geodesy and Astrometry (IVS) for a consistent modelling of this effect in its routine product generation. For the largest telescopes, the annual cycle of thermal expansion may change the height of the VLBI reference point by as much as 20 mm. However, for telescopes which are used in present-day IVS operations, the variations rather range from 4 to 6 mm.  相似文献   

Advances in understanding of the mechanism for generation of earthquake thermal precursors detected by satellites     

Arun K. Saraf  Vineeta Rawat  Swapnamita Choudhury  Sudipta Dasgupta  Josodhir Das 《International Journal of Applied Earth Observation and Geoinformation》2009

Stresses building up during an earthquake preparation phase also manifest themselves in the form of a so called increased land surface temperature (LST) leading to a thermal precursor prior to the earthquake event. This phenomenon has now been validated by our observations of short-term thermal anomalies detected by infrared satellite sensors for several recent past earthquakes around the world. The rise in infrared radiance temperature was seen to vary between 5 and 12 °C for different earthquakes. We discuss in this paper different explanations for the generation of such anomalies that have been offered. Emission of gases due to the opening and closure of micropores upon induced stresses and also the participation of ground water have been propounded as a possible cause for generation of thermal anomalies. Seismo-ionosphere coupling, by which gases like radon move to the earth–atmosphere interface and cause air ionization thus bringing about a change in air temperature, relative humidity, etc., has been put forth by some workers. A mechanism of low frequency electromagnetic emission was tested and experimented by scientists with rock masses in stressed conditions as those that exist at tectonic locations. The workers proposed the positive hole pair theory, which received support from several scientific groups. Positive holes (sites of electron deficiency) are activated in stressed rocks from pre-existing yet dormant positive hole pairs (PHPs) and their recombination at rock–air interface leads to a LST rise. A combination of remote sensing detection of rock mechanics behavior with a perception of chemistry and geophysics has been applied to propose the remote sensing rock mechanics theory. Remote sensing detections of such anomalies confirm so far proposed lab theories for such a hotly debated field as earthquake precursor study by providing unbiased observations with consistency in time and space distribution.  相似文献   

Modeling an atypical petroleum system: A case study of hydrocarbon generation,migration and accumulation related to igneous intrusions in the Neuquen Basin,Argentina     

F. Rodriguez Monreal  H.J. Villar  R. Baudino  D. Delpino  S. Zencich 《Marine and Petroleum Geology》2009

In the Altiplanicie del Payún area (Neuquen Basin, Argentina), immature source rock sections intruded by up to 600 m thick Tertiary laccoliths show full spectrum maturity aureoles over hundreds of meters from the contacts. Commercial oil accumulations (20–33°API) and oil shows are located along the entire column, both in sandstone/carbonate and fractured igneous reservoirs. A challenging numerical model that included the emplacement of the intrusive bodies, with extreme temperature ranges and unusually short calculation time steps, has been done with the aim to better understand hydrocarbon generation and migration processes related to these thermal anomalies.  相似文献